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Acetic acid is too weak an acid to provide the desired acidity in the solution, The reaction at room temperature is slow because of the equilibrium nature of this reaction. CO2 is highly soluble in water and thus heating removes all dissolved carbondioxide out of the solution driving the reaction in forward direction.

2KMnO4 + 5 H2C2O4 + 3H2SO4 = 2MnSO4 + K2SO4 + 10 CO2 + 8H2O

2MnO4¯ + 10 C2O42¯+ 16H+ = 2Mn2+ + 10 CO2 + 8H2O

at low temperature, the reduction of permanganate may not be complete producing Mn(III) (in the form [Mn(C2O4)3]3-).This complex however breaks on heating and hence reaction proceeds smoothly.

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5mo ago

Acetic acid is heated before titration with potassium permanganate to increase its reactivity and to speed up the reaction. Heating helps to ensure that the titration will proceed at a reasonable rate, allowing for more accurate and precise results.

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Q: Why acetic acid is heated before titration with potassium permagnate?
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Why is the vinegar diluted before titration?

Vinegar is diluted before titration to ensure the concentration of acetic acid in the solution is within the working range of the titration method being used. Dilution also helps in achieving more accurate and precise results by making it easier to measure small volumes of the solution during titration.


Why potassium oxalate is acidified before titration?

If the temperature is too low (below 55 degrees celsius), the interaction between the oxalate and the potassium permanganate will move too slow as to be used as a practical lab experiment. *** Above 60 degrees celsius, oxalate acid begins to decompose, so it's important to stay in this range.


Why do we heat KSCN Fe solution befor titration with EDTA?

Heating the KSCN Fe solution before titration with EDTA helps to break down any complex formations involving iron and potassium thiocyanate. This ensures that the titration accurately measures the amount of iron present in the solution by allowing EDTA to chelate with the iron ions more effectively.


What is the scout titration?

The scout titration is a preliminary titration carried out to estimate the approximate endpoint in a titration experiment before performing the actual titration. It helps in determining the approximate volume of titrant required for the main titration to avoid overshooting the endpoint.


Why the solution is boiled before titration?

Boiling the solution before titration helps to remove any dissolved gases that may interfere with the titration process. Additionally, heating the solution can help to dissolve the solute more effectively and improve the accuracy of the titration results.

Related questions

Why is the vinegar diluted before titration?

Vinegar is diluted before titration to ensure the concentration of acetic acid in the solution is within the working range of the titration method being used. Dilution also helps in achieving more accurate and precise results by making it easier to measure small volumes of the solution during titration.


Why potassium oxalate is acidified before titration?

If the temperature is too low (below 55 degrees celsius), the interaction between the oxalate and the potassium permanganate will move too slow as to be used as a practical lab experiment. *** Above 60 degrees celsius, oxalate acid begins to decompose, so it's important to stay in this range.


Why do we heat KSCN Fe solution befor titration with EDTA?

Heating the KSCN Fe solution before titration with EDTA helps to break down any complex formations involving iron and potassium thiocyanate. This ensures that the titration accurately measures the amount of iron present in the solution by allowing EDTA to chelate with the iron ions more effectively.


What is the scout titration?

The scout titration is a preliminary titration carried out to estimate the approximate endpoint in a titration experiment before performing the actual titration. It helps in determining the approximate volume of titrant required for the main titration to avoid overshooting the endpoint.


Why the solution is boiled before titration?

Boiling the solution before titration helps to remove any dissolved gases that may interfere with the titration process. Additionally, heating the solution can help to dissolve the solute more effectively and improve the accuracy of the titration results.


What is pilot titration?

Pilot titration is a preliminary test to determine the approximate endpoint of a titration process before conducting the actual titration. It helps in estimating the volume of titrant needed for the main titration, ensuring more accurate and efficient results. The data obtained from a pilot titration can help in planning and executing the main titration with greater precision.


Why heat citric acid before titration?

Heating citric acid before titration is done to help dissolve the solid citric acid more effectively in the solution. This ensures that the titration reaction occurs uniformly and the results are accurate. Additionally, heating can also help increase the rate of the reaction, making the titration process faster.


Why is it necessary to establish a blank titration before the reaction?

Establishing a blank titration allows you to account for any impurities or contaminants in the titration procedure or equipment, which could affect the accuracy of your results. By performing a blank titration, you can isolate the contribution of these factors and subtract them from your subsequent titration measurements to ensure the accuracy of your results.


Why is the outside of the burette wiped with paper towel before titration?

The outside of the burette is wiped with a paper towel before titration to ensure that any liquid droplets on the outer surface do not affect the accuracy of the titration by inadvertently entering the solution being titrated. This helps to prevent contamination and ensure precise measurements are obtained during the titration process.


Why is a solution containing a metal ion buffered before titration with EDTA?

Buffering the solution containing a metal ion before titration with EDTA helps maintain a constant pH, which is crucial for the accuracy and precision of the titration. The buffering prevents large pH changes that could affect the formation of metal-EDTA complexes and lead to errors in the titration results.


Why before doing titration conical flask is not rinsed?

The conical flask is not rinsed before performing titration because doing so could dilute the solution and alter the concentration, affecting the accuracy of the titration. It is important to maintain the concentration of the solution as accurately as possible for precise results.


Why KmnO4 is used as self indicator?

As we all know that the potassium permanganate (KMnO4) is the dark purple color solution ...and in titration it become colorless ....so when the titration is completed ...and the other single drop of KMnO4 solution produce pinkish colour in a beaker ...which indicate that the reaction was completed just a single drop before .. we use indicator in a a reaction in order to indicate ...but we dont used indicator in titration with KMnO4 because it also indicate us by changing its color ...colorless to pink