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due to inert pair effect

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12y ago
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7mo ago

SnCl2 is more stable than SnCl4 because of the lower oxidation state of tin (+2 in SnCl2 compared to +4 in SnCl4). The lower oxidation state of tin in SnCl2 leads to a higher stability due to less repulsion between the electrons. Additionally, the bond energy in the Sn-Cl bonds of SnCl2 is stronger than that in SnCl4, contributing to its stability.

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Q: Why SnCl2 is more stable than SnCl4?
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SnCl4 is more covalent than SnCl2 because SnCl4 has a greater electronegativity difference between tin and chlorine atoms compared to SnCl2. This results in stronger polarity in the Sn-Cl bonds, making SnCl4 more covalent. Additionally, SnCl4 has more Cl atoms surrounding the central Sn atom, leading to a higher charge density and more covalent character in its bonds.


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