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due to inert pair effect

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Why sncl4 more covalent than sncl2?

SnCl4 is more covalent than SnCl2 primarily due to the higher oxidation state of tin in SnCl4, which leads to a greater polarization of the chloride ions. The Sn4+ ion has a stronger positive charge, attracting the electron cloud of the Cl- ions more significantly, enhancing covalent character. In contrast, SnCl2, with Sn2+, exhibits less polarization and therefore has a greater ionic character. This difference in charge and polarization explains the greater covalent nature of SnCl4 compared to SnCl2.


How sncl4 more covalent than sncl2?

The halides in higher oxidation state posses high charge and are smaller in size as compared to the lower oxidation state halides.Thus, in higher oxidation halides the charge/radius ratio is higher which contribute to the increase in polarisation and consequently these are more covalent.(--AK)


Are the Sn-Cl bond polar or non polar in SnCl4?

They're polar, because they have different electronegativity values, so each atom attracts the electons with different "strenght".


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