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4 hydroxybenzoic acid is para directing group whereas 2 is ortho directing group. thus at para, the two groups i.e. alcohol and carboxyl are far apart and thus dont show steric hinderance. therefore para directing group is a stable and as a result less acidic.

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12y ago
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5mo ago

4-hydroxybenzoic acid is less acidic than 2-hydroxybenzoic acid because of the position of the hydroxyl group. In 2-hydroxybenzoic acid, the hydroxyl group is closer to the carboxylic acid group, enabling it to donate a proton more easily. This proximity stabilizes the negative charge on the conjugate base, making 2-hydroxybenzoic acid more acidic than 4-hydroxybenzoic acid.

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Q: Why 4-hydroxybenzoic acid is less acidic than 2-hydroxybenzoic acid?
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