This is a reaction that takes place on its own without an external force and another reaction needed to drive it. (It might not take place very quickly, however.) An iron nail rusting is spontaneous. Wood burning is spontaneous (even though you you often would use a spark to start it burning, it keeps on burning by itself.) Recharging a battery is a non-spontaneous reaction. It requires a continual supply of current to keep the reaction going.
A spontaneous reaction is one that occurs without the need for external assistance or input. It proceeds on its own accord due to a favorable change in entropy and/or enthalpy. It does not necessarily mean the reaction happens quickly, but rather that it can occur under the given conditions without added energy input.
In order to determine whether a chemical reaction is spontaneous, one has to consider both entropy and the enthalpy of the reaction in the form of Gibbs free energy. When Gibbs Free Energy takes a negative value, the reaction is said to be spontaneous and will freely occur without further input. If Gibbs Free Energy is positive, energy in some form will need to be put into the system to get it to react (electrolysis)
G = dH - TdS
dH= enthalpy ( in joules)
dS = entropy (jol/K)
T= temperature in K
G = gibbs free energy (jol/K)
These are all values found in the index of a chemistry book
To calculate for a chemical reaction, one considers the combined values of H and S for the products and reactants in order to derive the equation for the full gibbs free energy.
And always remember reactants - products
ex 2Na + Cl2------> 2NaCl
G= H - ST
g=[ (2dH NaCl) - (2dH Na + dH Cl2) ] - 273K[ (2dS NaCl) - (2dS Na + dS Cl2)]
If H were to take a high positive value, the reaction would need a lot of heat in order to make the value of TS greater than the value of H so that G is negative.
If the value of S is very large negativevalue then a really small T value would need to be achieved to compensate.
A spontaneous reaction.
A reaction that produces heat
In a fuel cell, the overall redox reaction is spontaneous, meaning it proceeds on its own without an external power source. The electrode reactions that occur at the anode and cathode are also spontaneous, as they involve the transfer of electrons from the fuel to the oxidant. This spontaneous reaction generates electrical energy that can be used to power devices.
The difference can be clarified by entropy (the second rule of thermodynamics).The reaction is more spontaneous with higher entropy, for the reactions that occur spontaneously the entropy is higher than for the ones that do not.
It is not spontaneous.
a non spontaneous reaction is a reaction that doesnt occur naturally and it normally tends to favor the reactants of a chemical reaction. Another thing is that it doesnt really produce free energy
spontaneous redox reaction
Which of the following (what)?
It is not spontaneous.
A spontaneous reaction.
The spontaneity of a reaction is determined by the sign of the Gibbs free energy (ΞG). If both enthalpy (H) and entropy (S) are positive, the reaction can be spontaneous at high temperatures where the TΞS term outweighs the positive ΞH term, resulting in a negative ΞG. This means the reaction will be spontaneous at elevated temperatures.
Candle burning is a spontaneous reaction. It is an exothermic reaction that occurs naturally and releases heat and light energy as the wax is being oxidized in the presence of oxygen from the air.
Hf, products > hf, reactants
A reaction that produces heat
A reaction is spontaneous if the Gibbs free energy change (ΞG) is negative. This means that the reaction can proceed without external energy input. In contrast, a reaction is nonspontaneous if ΞG is positive, meaning external energy is needed for the reaction to occur.
A neutralization reaction has as reactants a base and an acid and as products water and a salt.
An acid-base reaction that leaves no excess H+ or OH-