An ylide is a neutral molecule containing both a positive and negative charge on adjacent atoms, typically a carbanion adjacent to a positively charged atom such as phosphorus or sulfur. Ylides are important in organic chemistry as they can undergo reactions like the Wittig reaction to form alkenes.
The synthesis of E and Z α-phenylcinnamic acid can be achieved through the Wittig reaction, which involves the reaction of an aldehyde or ketone with a phosphonium ylide to form an alkene. By selecting appropriate reactants with specific stereochemistry, either the E or Z isomer can be obtained. Moreover, the stereochemistry of the product can be controlled by the choice of the phosphonium ylide used in the reaction.
In the Swern oxidation reaction, oxalyl chloride reacts with dimethyl sulfoxide (DMSO) to form an electrophilic sulfuranyl chloride intermediate, which in turn oxidizes the alcohol substrate to an aldehyde or ketone. This reaction proceeds through a two-step process involving a cyclic transition state.
An amine ylide is another name for an ammonium ylide.
An ammonium ylide is any dipolar organic compound of general formula R3N+-C-R2.
How about ylide? Seriously, this is a real word; it's a type of chemical compound.
The synthesis of E and Z α-phenylcinnamic acid can be achieved through the Wittig reaction, which involves the reaction of an aldehyde or ketone with a phosphonium ylide to form an alkene. By selecting appropriate reactants with specific stereochemistry, either the E or Z isomer can be obtained. Moreover, the stereochemistry of the product can be controlled by the choice of the phosphonium ylide used in the reaction.
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In the Swern oxidation reaction, oxalyl chloride reacts with dimethyl sulfoxide (DMSO) to form an electrophilic sulfuranyl chloride intermediate, which in turn oxidizes the alcohol substrate to an aldehyde or ketone. This reaction proceeds through a two-step process involving a cyclic transition state.