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If the ∆H is positive and the ∆S is positive, then the reaction is entropy driven. If the ∆H is negative and the ∆S is negative, then the reaction is enthalpy driven. If ∆H is positive and ∆S is negative, then the reaction is driven by neither of these. If ∆H is negative and ∆S is positive, then the reaction is driven by both of these.

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What is the relationship between enthalpy, entropy, and free energy in a chemical reaction?

In a chemical reaction, enthalpy, entropy, and free energy are related. Enthalpy is the heat energy exchanged during a reaction, entropy is the measure of disorder or randomness, and free energy is the energy available to do work. The relationship between these three factors is described by the Gibbs free energy equation: G H - TS, where G is the change in free energy, H is the change in enthalpy, S is the change in entropy, and T is the temperature in Kelvin. This equation shows that for a reaction to be spontaneous, the change in free energy must be negative, meaning that the enthalpy change and entropy change must work together in the right direction.


What is the relationship between Gibbs free energy and enthalpy in a chemical reaction?

In a chemical reaction, the relationship between Gibbs free energy and enthalpy is described by the equation G H - TS, where G is the change in Gibbs free energy, H is the change in enthalpy, T is the temperature in Kelvin, and S is the change in entropy. This equation shows that the Gibbs free energy change is influenced by both the enthalpy change and the entropy change in a reaction.


What could make G become negative at a given enthalpy and entropy?

Changing the temperature


Is polymerization endothermic or exothermic?

Polymerization can be either endothermic or exothermic, depending on the specific monomers and reaction conditions involved. Some polymerization reactions release energy (exothermic), while others may require energy input (endothermic) to overcome activation barriers.


What is the relationship between the enthalpy h and entropy s of a reaction that is spontaneous at higher temperatures but not at lower temperatures?

The relationship between enthalpy (H) and entropy (S) is described by the Gibbs free energy equation, ΔG = ΔH - TΔS, where ΔG is the change in Gibbs free energy, ΔH is the change in enthalpy, T is the temperature in Kelvin, and ΔS is the change in entropy. For a reaction to be spontaneous at higher temperatures but not at lower temperatures, the entropy term (TΔS) must dominate over the enthalpy term (ΔH) in the Gibbs free energy equation. This suggests that the increase in entropy with temperature plays a more significant role in driving the reaction towards spontaneity than the enthalpy change.

Related Questions

What is the relationship between enthalpy, entropy, and free energy in a chemical reaction?

In a chemical reaction, enthalpy, entropy, and free energy are related. Enthalpy is the heat energy exchanged during a reaction, entropy is the measure of disorder or randomness, and free energy is the energy available to do work. The relationship between these three factors is described by the Gibbs free energy equation: G H - TS, where G is the change in free energy, H is the change in enthalpy, S is the change in entropy, and T is the temperature in Kelvin. This equation shows that for a reaction to be spontaneous, the change in free energy must be negative, meaning that the enthalpy change and entropy change must work together in the right direction.


What is the relationship between Gibbs free energy and enthalpy in a chemical reaction?

In a chemical reaction, the relationship between Gibbs free energy and enthalpy is described by the equation G H - TS, where G is the change in Gibbs free energy, H is the change in enthalpy, T is the temperature in Kelvin, and S is the change in entropy. This equation shows that the Gibbs free energy change is influenced by both the enthalpy change and the entropy change in a reaction.


What could make G become negative at a given enthalpy and entropy?

Changing the temperature


How does gibbs energy relate to the changes in ethalpy and ethropy?

Gibbs energy accounts for both enthalpy (heat) and entropy (disorder) in a system. A reaction will be spontaneous if the Gibbs energy change is negative, which occurs when enthalpy is negative (exothermic) and/or entropy is positive (increased disorder). The relationship between Gibbs energy, enthalpy, and entropy is described by the equation ΔG = ΔH - TΔS, where T is temperature in Kelvin.


Is polymerization endothermic or exothermic?

Polymerization can be either endothermic or exothermic, depending on the specific monomers and reaction conditions involved. Some polymerization reactions release energy (exothermic), while others may require energy input (endothermic) to overcome activation barriers.


What is the relationship between the enthalpy h and entropy s of a reaction that is spontaneous at higher temperatures but not at lower temperatures?

The relationship between enthalpy (H) and entropy (S) is described by the Gibbs free energy equation, ΔG = ΔH - TΔS, where ΔG is the change in Gibbs free energy, ΔH is the change in enthalpy, T is the temperature in Kelvin, and ΔS is the change in entropy. For a reaction to be spontaneous at higher temperatures but not at lower temperatures, the entropy term (TΔS) must dominate over the enthalpy term (ΔH) in the Gibbs free energy equation. This suggests that the increase in entropy with temperature plays a more significant role in driving the reaction towards spontaneity than the enthalpy change.


True or False A large positive value of entropy tends to favor products of a chemical reaction?

True. A large positive value of entropy indicates an increase in disorder in a system, favoring products of a chemical reaction due to the higher entropy being associated with a higher number of possible microstates for the products compared to the reactants.


What makes chemical reaction spontaneous?

A chemical reaction is spontaneous if it releases energy in the form of heat or light, or if it increases the disorder (entropy) of the system. This can happen when the products of the reaction are more stable or have lower energy than the reactants. The key factor is whether the reaction can proceed with a net decrease in free energy.


When graphing enthalpy and entropy what variables are included?

In a graph of enthalpy versus temperature, the enthalpy of a substance is plotted on the y-axis, while the temperature is plotted on the x-axis. When graphing entropy versus temperature, the entropy of a substance is plotted on the y-axis while the temperature is plotted on the x-axis.


What is H in the equation G H TS?

The change in entropy between products and reactants in a reaction


What is the value equal to the enthalpy minus temperature times entropy?

The value you are referring to is the Gibbs free energy, which is equal to the enthalpy minus the temperature multiplied by the entropy: ΔG = ΔH - TΔS. This equation is used to determine if a reaction is spontaneous under certain conditions.


What is the significance of the Gibbs energy equation in determining the spontaneity of a chemical reaction?

The Gibbs energy equation helps determine if a chemical reaction will occur spontaneously by considering the change in enthalpy and entropy of the system. If the Gibbs energy is negative, the reaction is spontaneous.