By titration (manual or electrochemical) with a base and an indicator.
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In acidic medium, the equivalence point can be detected using an acid-base indicator that undergoes a color change at the pH corresponding to the equivalence point. Alternatively, a pH meter can be used to monitor the pH of the solution during the titration, with the equivalence point identified as the point of maximum change in pH.
In a titration experiment, the equivalence point can be found using methods such as using a pH meter to detect a sudden change in pH, using an indicator that changes color at the equivalence point, or using a titration curve to identify the point of neutralization.
At the equivalence point, all ammonia (NH3) is converted to ammonium ion (NH4+). The solution contains ammonium chloride (NH4Cl), a salt of a weak acid (NH4+) and a strong acid (Cl-), making the solution acidic. The ammonium ion hydrolyzes in water to form NH4+ + H2O -> NH3 + H3O+. Therefore, the pH at the equivalence point will be less than 7, indicating an acidic solution.
The equivalence point in a titration is calculated by determining the point at which the moles of the titrant added are equal to the moles of the analyte being titrated. This is typically done by monitoring a change in pH or using an indicator to detect the endpoint of the reaction.
The pH meter can detect the equivalence point in a titration by monitoring a sudden change in pH value. At the equivalence point, the number of moles of acid and base are equal, causing a rapid increase or decrease in pH depending on the reaction. This abrupt change marks the completion of the reaction and helps determine the exact volume of titrant needed to reach the equivalence point.
A strong diprotic acid titration curve typically shows two distinct equivalence points, indicating the presence of two acidic hydrogen ions that can be neutralized. The curve will have a steeper slope at the equivalence points and a flatter region in between, reflecting the buffering capacity of the acid. The pH at the first equivalence point will be lower than at the second equivalence point due to the differing strengths of the two acidic hydrogen ions.