The boiling point of a substance can be determined by heating the substance and measuring the temperature at which it changes from a liquid to a gas. This temperature is known as the boiling point.
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To determine the substance with the highest boiling point in a set of compounds, you need to compare their molecular structures and intermolecular forces. The substance with stronger intermolecular forces, such as hydrogen bonding or dipole-dipole interactions, will typically have a higher boiling point. Additionally, larger molecules tend to have higher boiling points due to increased surface area for intermolecular interactions.
To determine the boiling point using simple distillation, one can heat a liquid mixture in a distillation apparatus and collect the vapor that is produced. The temperature at which the vapor condenses back into a liquid is the boiling point of the substance. This can be measured using a thermometer placed in the distillation apparatus.
The substance with the highest boiling point is the one you should choose.
The melting and boiling points of a substance are characteristic physical properties that can be used to assess purity. A pure substance will have a sharp melting or boiling point, occurring at a specific temperature range. Impurities tend to disrupt the orderly arrangement of particles in the substance, leading to a broader or lower melting/boiling point compared to the pure form. By comparing the experimental melting or boiling point of a sample to the literature values for the pure substance, one can determine the level of purity.
To determine the boiling point from vapor pressure, one can use the Clausius-Clapeyron equation, which relates the vapor pressure of a substance to its temperature. By plotting the natural logarithm of the vapor pressure against the reciprocal of the temperature, the boiling point can be determined as the temperature at which the vapor pressure equals the atmospheric pressure.