A reaction will be spontaneous at a given temperature if the Gibbs free energy change (ΔG) is negative. ΔG = ΔH - TΔS. As ΔH = -92 kJ/mol and ΔS = -0.199 kJ/(mol.K), plug these values into the equation along with the temperature to solve for ΔG. If ΔG is negative, the reaction will be spontaneous at that temperature.
The condition for a reaction to be spontaneous is ΔG < 0, where ΔG = ΔH - TΔS. At the temperature where ΔG becomes negative, the reaction will be spontaneous. You can calculate this temperature using the given values of ΔH and ΔS.
For the reaction to occur at room temperature, an external energy source must be provided to drive the reaction, and the reaction will absorb heat from the surroundings. The reaction is non-spontaneous because it does not occur naturally without intervention.
A high temperature can make a nonspontaneous reaction spontaneous by providing enough energy to overcome the activation energy barrier, allowing the reaction to proceed. At low temperatures, the kinetic energy of the molecules may not be sufficient for them to react, but increasing the temperature can provide the necessary energy for the reaction to occur spontaneously.
if H and S are both negative
A high temperature could make a reaction spontaneous that was nonspontaneous at low temperature when the increase in entropy due to the reaction outweighs the increase in enthalpy. At higher temperatures, the TΔS term in the Gibbs free energy equation becomes more dominant, leading to a positive ΔG becoming negative, thus making the reaction spontaneous.
The condition for a reaction to be spontaneous is ΔG < 0, where ΔG = ΔH - TΔS. At the temperature where ΔG becomes negative, the reaction will be spontaneous. You can calculate this temperature using the given values of ΔH and ΔS.
Increasing the temperature makes a reaction spontaneous in some situations.
A high temperature will make it spontaneous.
To determine the temperature at which the decomposition of KClO4 is spontaneous, you need to know the Gibbs free energy change (∆G) for the reaction. If ∆G is negative, the reaction is spontaneous. Use the equation ∆G = ∆H - T∆S, where ∆H is the enthalpy change, ∆S is the entropy change, and T is the temperature in Kelvin. Set ∆G to 0 and solve for T to find the temperature at which the decomposition becomes spontaneous.
if H and S are both negative
The reaction is spontaneous below 554.8/0.1975 K.
For the reaction to occur at room temperature, an external energy source must be provided to drive the reaction, and the reaction will absorb heat from the surroundings. The reaction is non-spontaneous because it does not occur naturally without intervention.
A high temperature can make a nonspontaneous reaction spontaneous by providing enough energy to overcome the activation energy barrier, allowing the reaction to proceed. At low temperatures, the kinetic energy of the molecules may not be sufficient for them to react, but increasing the temperature can provide the necessary energy for the reaction to occur spontaneously.
if H and S are both negative
the answer is 400
A high temperature could make a reaction spontaneous that was nonspontaneous at low temperature when the increase in entropy due to the reaction outweighs the increase in enthalpy. At higher temperatures, the TΔS term in the Gibbs free energy equation becomes more dominant, leading to a positive ΔG becoming negative, thus making the reaction spontaneous.
The reverse reaction is endothermic and nonspontaneous.