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1 ppm iron is equal to 1 part iron in 1 million parts of solution

The exact procedure for preparing the solution will depend on what you are using as your source of iron, but in general you start by deciding what volume of 1 ppm solution you want to make first.

Let's say you want to make 1L of 1ppm iron solution. With aqueous solutions (where density stays approximately 1 mg per mL), 1ppm = 1 mg / 1 million mg = 1 mg/kg = 1 mg/L.

So you want to put 1 mg of iron into 1 L of water. Keep in mind that it has to be 1 mg of iron specifically and not necessarily 1 mg of the iron-containing compound that you might be using. Iron has an Atomic Mass of 55.845 g/mol, which can be written as 0.017907 mol/g. Therefore there is 0.017907 mmol per mg of iron. You want to have 0.017907 mmoles of iron in the solution to make it 1 ppm.

Now you just have to figure out what quantity of your iron-containing compound you need to add in order to have 0.017907 mmoles of iron in the solution. Let's imagine that you are using iron (ii) chloride, for example, which has a molar mass of 126.751 g/mol in the anhydrous form. To get 0.017907 mmoles of iron from this compound, you need to get 0.017907 mmoles of the compound itself since there is 1 mole of iron in 1 mole of the compound.

0.017907 mmoles of iron (ii) chloride has a mass of about 0.002270 g (calculated from its molar mass)

At this point if you have any analytical laboratory experience, you would realize that 0.002 g is way too small of a quantity to measure reliably on any normal analytical balance. Therefore, you will need to make a more concentrated solution first and then dilute it down to 1 ppm.

For example, you could measure out 2 g of iron (ii) chloride and dissolve it in 1 L of water to make a 1000 ppm iron solution. Then you would dilute this solution down in steps of 10 until you get down to 1 ppm (in essence, 3 dilutions, 10x10x10).

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Q: 1 How do you make 1 ppm solution of iron?
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