mineral pigments
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You should be able to rinse the paint brushes and rollers out with water to use them again. Make sure that you do this immediately after finishing using the brushes. If you do not then the paint will harden on the brushes and you will not be able to use them any more.
Brushes, oil paint, a canvas.
They used sticks as paint brushes and used animal blood as paint.
No. There are special brushes for oil based paint.