No. Poly and paint are incompatible. Instead use liquid floor wax. It's easier to work with and will give you a longer lasting surface that doesn't stick to paPer when wet. You can continue to re coat for maintenance. Great for tabletops shelves or painted floors.
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Only if the 'flat paint' is water based too.
It is water based paint that has no sheen to it and does not clean well. Usually used on ceilings.
"flat" paint is flat flat -- no sheen at all. My understanding is that "flat enamel" has a very slight sheen -- like about 6%, which supposedly makes it a little easier to clean than the flat flat paint. But, it's pretty hard to distinguish one from the other.
Of the two paints you are going to try mixing, a water based paint (latex), with a spirit based (possibly methalated) . Not a good idea as they will separate. DO NOT MIX! On the containers for these paints you will be told how to wash your brushes ie.. Water for Latex. Turpintine, or Varsol for the Oil based paints and stains. Again, Oil and Water do NOT MIX!!!
Do you realize that you can get FLAT ACRYLIC PAINT. Flat paint refers to the gloss level. You may want Gloss, Satin, Lowsheen or Flat. Acrylic paint on the other hand refers to what the paint is based on or what binder is being used. Acrylic paint is also refered to as waterbased paint. You most likely are referring to putting flat acrylic over lowsheen or gloss acrylic. In answer to your question - as long as they are both acrylic than you will not have any problems. I am in this answer assuming that you are referring you house paints. If not than the same principle applies - acrylic over acrylic is fine. To keep acrylic from going glossy just don't polish it.