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Nitrogen, has 5 electrons in its outer shell, Boron has only 3.

When Nitrogen Bonds with 3 Chlorine atoms, to become NCl3, it still has 2 electrons left in its outer shell, which form a lone pair. As these could bond to a single proton, (i.e. hydrogen without its electron) they have to be shown in the diagram.

NCl3 therefore has 3 bonds and 1 lone pair, so 4 things to show in the bond diagram. Making it trigonal pyramidal.

However, Boron only has 3 electrons to bond. As these are all used up in the bonds with chlorine, there are only 3 bonding pairs to show in the diagram. Therefore it is trigonal planar.

NCl3 has bond angles of 107 degrees

whereas

BCl3 has bond angles of 120 degrees.

Hope this helps.

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11y ago

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More answers

Nitrogen trichloride is pyramidal because of its lone pair of electrons, which causes the nitrogen atom to distort the molecule into a pyramidal shape to minimize electron repulsion. Boron trichloride lacks a lone pair on the boron atom, resulting in a trigonal planar shape due to the three bonding pairs of electrons being spread evenly in the plane around the boron atom.

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AnswerBot

10mo ago
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There are three bonding pairs and one bonding pair of electron around the central nitrogen atom. The ammonia molecule is trigonal pyramidal as non-bonding electron pairs repel more than bonding electron pairs.

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10y ago
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because the lone pair shoves the other atoms closer to each other

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14y ago
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There is a lone pair.It makes NH3 pyramidal.

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Wiki User

10y ago
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The nitrogen in ammonia has 5 valence electrons and bonds with three hydrogen atoms to complete the octet.

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10y ago
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There is a lone pair.It repels the bonds and make the shape pyramidal.

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Wiki User

11y ago
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NH3 has a lone pair.So NH3 is pyramidal.

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Wiki User

10y ago
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Q: Why is the nitrogen trichloride molecule pyramidal shape but boron trichloride molecule trigonal planar?
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