If you require a passport urgently in the United Kingdom then you must make an appointment at the Passport Customer Service Centre. There is an extra fee for an urgent passport. However, if it is not urgent, you may apply by post. All of the relevant information for applying for a passport, including documentation needed and how much it will cost, can be found online on the Government website. You may also be able to obtain information by inquiring in your local Post Office.
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If you are a UK citizen - from the Passport Office. If you are a non-UK citizen - from your embassy.
You can get a passport application form from the nearest Post Office branch. You can also get a passport application form online. The site, however, will depend on where you are from.