Voyager 2 spacecraft headed toward Neptune in the year 1989. But I have no idea if the voyager photograph Neptune's rings.
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The Voyager 2 observation phase of Neptune began on 5-Jun-1989, and ended on 2-Oct-1989, with the closest approch on 25-Aug-1989 (29,240km). The ring system would have been phootgraphed several times throughout this timeframe.
Voyager 2 spacecraft headed toward Neptune in the year 1989. But I have no idea if the voyager photograph Neptune's rings.