Officially the 'Adopt-a-Shelter-Pet' stamp/s are called the 'Animal Rescue' stamps with the subtitle of 'Adopt-a-Shelter-Pet' on the stamp. The 'Animal Rescue'stamps were issued (April 22, 2010) as Scott Catalog numbers4451-4460. These are cute stamps with pictures of cats and dogs. Yes the Post Office did stop making these stamps, but you still can purchase these stamps from dealers at a reasonable price.
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Yes the post office sells 10 cent stamps. Stamps are available in a wide variety of denominations and not all offices will have a full selection. You can mix and match as necessary, so if they don't have 10 cent stamps, you could buy two 5 cent stamps.
There is a current 20 cent US stamp . It is used to pay for the second ounces of
first class postage along with a forever (45 cent0 stamp). I do not know if every post office has them.
Yes the Post Office does sell collectable stamps. They have sold every stamp that has been created at one point or another.