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No - barley is one of the five grains listed in the Talmud that are expressly forbidden during Passover which, if they come into contact with water for more than 18 minutes during preparation, are termed chametz. Observant Jews believe that, if they eat chametx during Passover, they risk karet - spiritual excision, a punishment not unlike the Catholic excommunication.

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Q: Can you have barley on Passover?
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