|
|
| General |
| Name, Symbol,
Number |
radon, Rn, 86 |
| Chemical series |
noble gases |
| Group, Period,
Block |
18, 6, p |
| Appearance |
colorless |
| Standard atomic weight |
(222) g·mol−1 |
| Electron configuration |
[Xe] 4f14 5d10 6s2 6p6 |
| Electrons per shell |
2, 8, 18, 32, 18, 8 |
| Physical properties |
| Phase |
gas |
| Density |
(0 °C, 101.325 kPa)
9.73 g/L |
| Melting point |
202 K
(−71.15 °C, −96 °F) |
| Boiling point |
211.3 K
(−61.85 °C, −79.1 °F) |
| Critical point |
377 K, 6.28 MPa |
| Heat of fusion |
3.247 kJ·mol−1 |
| Heat of vaporization |
18.10 kJ·mol−1 |
| Heat capacity |
(25 °C) 20.786 J·mol−1·K−1 |
Vapor pressure
| P(Pa) |
1 |
10 |
100 |
1 k |
10 k |
100 k |
| at T(K) |
110 |
121 |
134 |
152 |
176 |
211 |
|
| Atomic properties |
| Crystal structure |
cubic face centered |
| Oxidation states |
0 |
| Electronegativity |
no data (scale Pauling) |
| Ionization energies |
1st: 1037 kJ/mol |
| Atomic radius (calc.) |
120 pm |
| Covalent radius |
145 pm |
| Miscellaneous |
| Magnetic ordering |
non-magnetic |
| Thermal conductivity |
(300 K) 3.61 m W·m−1·K−1 |
| CAS registry number |
10043-92-2 |
| Selected isotopes |
|
|
| References |
Radon (IPA: /ˈreɪdɒn/) is a chemical element that has the symbol Rn and
atomic number 86. Radon is a radioactive
noble gas that is formed by the decay of radium. It is one of
the heaviest gases and is considered to be a health hazard. The most stable isotope is
222Rn which has a half-life of 3.8 days and is used in radiotherapy. Radon is a significant contaminant that affects indoor air quality worldwide. Radon gas from natural sources can accumulate in buildings and
reportedly causes 21,000 lung cancer deaths per year in the United States alone.[1]
Notable characteristics
Essentially chemically inert but radioactive, radon is the heaviest noble gas and one of
the heaviest gases at room temperature. At standard
temperature and pressure radon is a colorless gas, but when it is cooled below its freezing point (202 K ; −71 °C ; −96 °F) it has a brilliant phosphorescence which turns
yellow as the temperature is lowered, and becomes orange-red at the temperatures air liquefies (below 93 K ; −180
°C).
Natural radon concentrations in Earth's atmosphere are so low that radon-rich
water in contact with the atmosphere will continually lose radon by volatilization.
Hence, ground water has a higher concentration of 222Rn than surface water, because it is continuously produced by radioactive decay of 226Ra present in rocks. Likewise, the saturated zone of a soil frequently has a higher radon content than the
unsaturated zone because of diffusional losses to the atmosphere.
History
Radon (named after radium) was discovered in 1900 by Friedrich Ernst Dorn, who
called it radium emanation. In 1908 William Ramsay and Robert Whytlaw-Gray, named it niton (Latin nitens meaning
"shining"; symbol Nt) and isolated it, determined its density, and determined that it was the heaviest known
gas. It has been called "radon" since 1923.
The first major studies of the health concern occurred in the context of uranium mining, first in the Joachimsthal region of Bohemia and then in the Southwestern United States during the early Cold War.
Because radon is a product of uranium, uranium mines have high concentrations of radon and its highly radioactive
daughter products. Many Native
Americans, Mormons, and other miners in the Four
Corners region contracted lung cancer and other pathologies as a result of high
levels of exposure to radon gas while mining uranium for the Atomic
Energy Commission in the mid-1950s. Safety standards instituted required expensive ventilation and as such were not widely
implemented or policed.
The danger of radon exposure in dwellings was discovered in 1984 with the case of Stanley Watras, an employee at the
Limerick nuclear power plant in Pennsylvania. Watras set off the radiation alarms on his way
into work for two weeks straight while authorities searched for the source of the contamination. They were shocked to find
that the source was astonishingly high levels of radon, around 100,000 Bq/m3 (2,700
pCi/L), in his house's basement and it was not related to
the nuclear plant. The risks associated with living in his house were estimated to be equivalent to smoking 135 packs of cigarettes every day. Following this event,
which was highly publicized, national radon safety standards were set, and radon detection and ventilation became a standard
homeowner concern.
Radon is the second most frequent cause of lung cancer, after cigarette smoking, and radon-induced lung cancer is thought to
be the 6th leading cause of cancer death overall.[2][3]
Occurrence
On average, there is one atom of radon in 1 x 1021 molecules of air.[citation needed] Radon can be found in some spring
waters and hot springs.[4] The towns of Boulder, Montana, Misasa, Japan, and Bad Kreuznach,
Germany boast radium-rich springs which emit radon.
Radon emanates naturally from the ground all over the world, particularly in regions with soils containing granite or shale. However, not all granitic regions are prone to high emissions
of radon. Depending on how houses are built and ventilated, radon may accumulate in basements and dwellings. The highest average
radon concentrations in counties in the U.S. are found in Iowa and in the Appalachian Mountains areas in southeastern Pennsylvania. [5]
Radon, along with other noble gases krypton and xenon, is also
produced during the operation of nuclear power plants. A small fraction of it leaks out of
the fuel, through the cladding and into the cooling water, from which it is scavenged. It is then routed to a holding tank where
it remains for a large number of half-lives. It is finally purged to the open air through a tall stack which is carefully
monitored for radiation level.
The European Union recommends that action should be taken starting from concentrations
of 400 Bq/m3 (11 pCi/L) for old houses and 200 Bq/m3 (5 pCi/L) for new ones. After publication of the North
American and European Pooling Studies, Health Canada has proposed a new guideline that
lowers their action level from 800 to 200 Bq/m3 (22 to 5 pCi/L).[6] The United States Environmental
Protection Agency (EPA) strongly recommends action for any house with a concentration higher than 148 Bq/m3 (4
pCi/L)[7], and encourages action starting at 74 Bq/m3 (2 pCi/L). EPA radon risk level tables including comparisons to other risks encountered in life are available
in their citizen's guide.[8] Nearly one in 15 homes in the
U.S. has a high level of indoor radon according to their statistics. The U.S. Surgeon General and EPA recommend all homes be
tested for radon.
Radon emitted from the ground has been shown to accumulate in the air if there is a meteorological inversion and little
wind.[9]
Compounds
Some experiments indicate that fluorine can react with radon and form radon fluoride. Radon clathrates have also been reported.
Isotopes
-
There are twenty known isotopes of radon. The most stable isotope is
222Rn, which is a decay product (daughter
product) of 226Ra, has a half-life of 3.823 days and emits alpha
particles. 220Rn is a natural decay product of thorium and is called “thoron.”
It has a half-life of 55.6 seconds and also emits alpha radiation. 219Rn is derived from actinium, is called “actinon,” is an alpha emitter and has a half-life of 3.96 seconds.
The full decay series of 238U which
produces natural radon is as follows (with half-lives):
238U (4.5 x 109 yr), 234Th (24.1 days), 234Pa (1.18 min), 234U (250,000 yr),
230Th (75,000 yr), 226Ra
(1,600 yr), 222Rn (3.82 days), 218Po (3.1 min),
214Pb (26.8 min), 214Bi (19.7 min), 214Po (164 µs), 210Pb (22.3 yr), 210Bi
(5.01 days), 210Po (138 days), 206Pb (stable).
Applications
Radon therapy
In the United States and Europe there are a few "radon spas," where people sit for
minutes or hours in a high-radon atmosphere in the belief that airborne radiation will invigorate or energize them. However,
there is no scientific evidence for this belief, nor any known biological mechanism by which such an effect could occur. In
addition, it conflicts with the internationally recognized standard that there is no
safe threshold for radiation exposure and that exposure should be limited to that "as low as
reasonably achievable" (ALARA).
Radioactive water baths have been applied since 1906 in Jáchymov, Czech Republic, but even before radon discovery they were used in Bad
Gastein, Austria. Hot radium-rich spring releasing radon is also used in traditional
Japanese onsen in Misasa,
Tottori prefecture. Drinking therapy is applied in Bad
Brambach, Germany. Inhalation therapy is carried out in Gasteiner-Heilstollen, Austria, in Kowary,
Poland and in Boulder, Montana, United States.
Hydrologic studies
Because of radon's rapid loss to air and comparatively rapid decay, radon is used in hydrologic research that studies the interaction between ground water and streams. Any significant concentration of radon in a stream is a good indicator that there are local inputs of
ground water.
Geologic studies
Some researchers have looked at elevated soil-gas radon concentrations, or rapid changes in soil or groundwater radon
concentrations, as a predictor for earthquakes. Results have been generally unconvincing but
may ultimately prove to have some limited use in specific locations.
Radon soil-concentration has been used in an experimental way to map buried close-subsurface geological faults, because
concentrations are generally higher over the faults. Similarly it has found some limited use in geothermal prospecting.
Atmospheric studies
Radon emanation from the soil varies with soil type and with surface uranium content, so outdoor radon concentrations can be
used to track air masses to a limited degree. This fact has been put to use by some atmospheric scientists.
Radon is a known pollutant emitted from geothermal power stations, though it disperses rapidly, and no radiological hazard has
been demonstrated in various investigations. The trend in geothermal plants is to reinject all emissions by pumping deep
underground, and this seems likely to ultimately decrease such radon hazards further. Radon is also used in dating of oil
contained soil because radon have a high affinity of oil like substance.
Health effects and epidemiology
The general effects of radon to the human body are caused by its radioactivity and consequent risk of radiation-induced
cancer. As an inert gas, radon has a low solubility in body fluids which lead to a uniform distribution of the gas throughout the
body.[10] Radon gas and its solid decay products are
carcinogens. The greatest health risks come from exposure to the inhaled solid radon gas
decay products that are produced during the radioactive decay of radon gas. Two of these decay products, polonium-218 and 214, present a significant radiologic hazard.[11] Once the radioactive decay products are inhaled into the lung, they
undergo further radioactive decay, releasing small bursts of energy in the form of alpha
particles that can either cause DNA breaks or create free radicals.[11]
Based on studies carried out by the National Academy of
Sciences in the United States, radon is the second most common cause of lung cancer after cigarette smoking, accounting
for 15,000 to 22,000 cancer deaths per year in the U.S.[12]
The Surgeon General of the United States has reported that over
20,000 Americans die each year of radon-related lung cancer.[13] The United States Environmental
Protection Agency (EPA) recommends homes be fixed if an occupant's long-term exposure will average 4 picocuries per liter (pCi/L) (148 Bq m−3) or higher.[14]
The most elaborate case-control epidemiologic radon study performed by R. William
Field and colleagues demonstrated a 50% increased lung cancer risk with prolonged radon exposure at the EPA's action level
of 4 pCi/L.[15] Iowa has the highest average radon
concentrations in the nation and a very stable population which added to the strength of the study. Pooled epidemiologic radon
studies[16][17] have also shown an increased lung cancer risk from radon below the EPA's action
level of 4 pCi/L.
It is unknown whether radon causes other types of cancer, but recent studies suggest a need for further studies to assess the
relationship between radon and leukemia.[18][19]
Testing and mitigation
ASTM E-2121 is a standard for reducing radon in homes as far as practicable below
4 picocuries per liter (pCi/L) in indoor air.[20][21]
Radon test kits are commercially available. The kit includes a collector that the user hangs in the lowest livable floor of
the house for 2 to 7 days. The user then sends the collector to a laboratory for analysis. The National Environmental Health
Association provides a list of radon measurement professionals.[22] Long term kits, taking collections for up to one year, are also available. An open land test kit
can test radon emissions from the land before construction begins. The EPA and the National Environmental Health Association have
identified 15 types of radon testing.[23] A
Lucas cell is one type of device.
Radon levels fluctuate naturally. An initial test might not be an accurate assessment of your home's average radon level.
Transient weather can affect short term measurements.[24]
Therefore, a high result (over 4 pc/l) justifies repeating the test before undertaking more expensive abatement projects.
Measurements between 4 and 10 pc/l warrant a long term radon test. Measurements over 10 pc/l warrant only another short term test
so that abatement measures are not unduly delayed. Purchasers of real estate are advised to delay or decline a purchase if the
seller has not successfully abated radon to 4 pc/l or less.
The National Environmental Health Association administers a voluntary National Radon Proficiency Program for radon
professionals consisting of individuals and companies wanting to take training courses and examinations to demonstrate their
competency.[25] A list of mitigation service providers is
available.[26] Indoor radon can be mitigated by sealing
basement foundations, water drainage, or by sub-slab de-pressurization. In severe cases, mitigation can use air pipes and fans to
exhaust sub-slab air to the outside. Indoor ventilation systems are more effective, but exterior ventilation can be
cost-effective in some cases. Modern construction that conserves energy by making homes air tight exacerbates the risks of radon
exposure if radon is present in the home. Older homes with more porous construction are more likely to vent radon naturally.
Ventilation systems can be combined with a heat exchanger to recover energy in the process of exchanging air with the outside.
Homes built on a crawl space can benefit from a radon collector installed under a radon barrier (a sheet of plastic that covers
the crawl space).
Notes
- ^ http://www.epa.gov/radon/pubs/citguide.html
- ^ S. Darby, D. Hill, R. Doll (2001). "Radon:
A likely carcinogen at all exposures". Annals of Oncology 12 (10): 27. DOI:10.1023/A:1012518223463.
- ^ http://www.cheec.uiowa.edu/misc/Webtop10.ppt
- ^ Radon Occurrence and Health Risk, R. William Field, Department of Occupational and
Environmental Health, University of Iowa.
- ^ http://eetd.lbl.gov/IEP/high-radon/USgm.htm
- ^ It's Your Health - Radon, Health Canada
- ^ Radiation information: radon.
United States Environmental Protection Agency (Oct 2006).
Retrieved on 2007-05-25.
- ^ A Citizen's Guide to Radon: The Guide to Protecting Yourself and Your Family from Radon, United States Environmental Protection Agency.
- ^ Daniel J. Steck, R. William Field, and Charles F. Lynch, "Exposure to
Atmospheric Radon", Environmental Health Perspectives, Volume 107, Number 2, February 1999. Online
version
- ^ Lindgren, 1989
- ^ a b Field, R. William (1999). Radon Occurrence and Health Risk (PDF).
Retrieved on 2007-08-17.
- ^ National Cancer
Institute (2004-07-13). Radon and Cancer: Questions and Answers. Retrieved on 2007-08-17.
- ^ Surgeon General Releases National Health Advisory On Radon (2005-01-13). Retrieved on
2007-08-17.
- ^ EPA (2007-08-08). United States Environmental Protection Agency: Radon. Retrieved on 2007-08-17.
- ^ Field,
R. W.; et al. (2000). "Residential radon gas exposure and lung cancer: The Iowa radon lung cancer study" (PDF). American Journal of
Epidemiology 151 (11): 1091-1102. PMID 10873134.
- ^ University of Iowa News Release (2006-05-05). Journal on Landmark Radon
Exposure Studies Co-edited By UI Researcher. Retrieved on 2007-08-17.
- ^ Krewski, D.; et al.. "Residential radon and
risk of lung cancer: A combined analysis of 7 North American case-control studies" (PDF). Epidemiology 16 (2):
137-45. DOI:10.1097/01.ede.0000152522.80261.e3.
- ^ Smith, B. J.; Zhang, L. & Field, W.R.
(2007). "Iowa radon leukaemia study: a hierarchical population risk model for spatially correlated exposure measured with
error.". Statistical Medicine E-published. PMID 17373673.
- ^ Rericha, V; Kulich M, Rericha R, Shore
DL, Sandler DP (2007). "Incidence of leukemia, lymphoma, and multiple myeloma in Czech uranium miners: a case-cohort study".
Environmental Health Perspectives 115 (4): A184-5. PMID 16759978.
- ^ http://www.epa.gov/iaq/radon/pubs/mitstds.html
- ^ http://www.astm.org/cgi-bin/SoftCart.exe/DATABASE.CART/REDLINE_PAGES/E2121.htm?L+mystore+xyan5063
- ^ http://www.radongas.org/Description_of_Radon_Measurement_Service.html
- ^ http://www.radongas.org/device.htm
- ^ http://www.radon.com/radon/mitigation.html
- ^ http://www.radongas.org/
- ^ http://www.radongas.org/Description_of_Radon_Mitigation_Services.html
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