matter

The Properties of Matter

The general properties of matter result from its relationship with mass and space. Because of its mass, all matter has inertia (the mass being the measure of its inertia) and weight, if it is in a gravitational field (see gravitation). Because it occupies space, all matter has volume and impenetrability, since two objects cannot occupy the same space simultaneously.

The special properties of matter, on the other hand, depend on internal structure and thus differ from one form of matter, i.e., one substance, to another. Such properties include ductility, elasticity, hardness, malleability, porosity (ability to permit another substance to flow through it), and tenacity (resistance to being pulled apart).

The States of Matter

Matter is ordinarily observed in three different states, or phases (see states of matter), although scientists distinguish three additional states. Matter in the solid state has both a definite volume and a definite shape; matter in the liquid state has a definite volume but no definite shape, assuming the shape of whatever container it is placed in; matter in the gaseous state has neither a definite volume nor a definite shape and expands to fill any container. The properties of a plasma, or extremely hot, ionized gas, are sufficiently different from those of a gas at ordinary temperatures for scientists to consider them to be the fourth state of matter. So too are the properties of the Bose-Einstein and fermionic condensates, which exist only at temperatures approximating absolute zero (−273.15°C), and they are considered the fifth and sixth states of matter respectively.

Early Theories of Matter

In ancient times various theories were suggested about the nature of matter. Empedocles held that all matter is made up of four “elements”—earth, air, fire, and water. Leucippus and his pupil Democritus proposed an atomic basis of matter, believing that all matter is built up from tiny particles differing in size and shape. Anaxagoras, however, rejected any theory in which matter is viewed as composed of smaller constituents, whether atoms or elements, and held instead that matter is continuous throughout, being entirely of a single substance.

Modern Theory of Matter

The modern theory of matter dates from the work of John Dalton at the beginning of the 19th cent. The atom is considered the basic unit of any element, and atoms may combine chemically to form molecules, the molecule being the smallest unit of any substance that possesses the properties of that substance. An element in modern theory is any substance all of whose atoms are the same (i.e., have the same atomic number), while a compound is composed of different types of atoms together in molecules.

Physical and Chemical Changes

The difference between a mixture and a compound helps to illustrate the difference between a physical change and a chemical change. Different atoms may also be present together in a mixture, but in a mixture they are not bound together chemically as they are in a compound. In a physical change, such as a change of state (e.g., from solid to liquid), the substance as a whole changes, but its underlying structure remains the same; water is still composed of molecules containing two hydrogen atoms and one oxygen atom whether it is in the form of ice, liquid water, or steam. In a chemical change, however, the substance participates in a chemical reaction, with a consequent reordering of its atoms. As a result, it becomes a different substance with a different set of properties.

Many of the physical properties and much of the behavior of matter can be understood without detailed assumptions about the structure of atoms and molecules. For example, the kinetic-molecular theory of gases provides a good explanation of the nature of temperature and the basis of the various gas laws and also gives insight into the different states of matter. Substances in different states vary in the strength of the forces between their molecules, with intermolecular forces being strongest in solids and weakest in gases. The force holding like molecules together is called cohesion, while that between unlike molecules is called adhesion (see adhesion and cohesion). Among the phenomena resulting from intermolecular forces are surface tension and capillarity. An even larger number of aspects of matter can be understood when the nature and structure of the atom are taken into account. The quantum theory has provided the key to understanding the atom, and most basic problems relating to the atom have been solved.

The Relationship of Matter and Energy

The atomic theory of matter does not answer the question of the basic nature of matter. It is now known that matter and energy are intimately related. According to the law of mass-energy equivalence, developed by Albert Einstein as part of his theory of relativity, a quantity of matter of mass m possesses an intrinsic rest mass energy E given by E = mc², where c is the speed of light. This equivalence is dramatically demonstrated in the phenomena of nuclear fission and fusion (see nuclear energy; nucleus), in which a small amount of matter is converted to a rather large amount of energy. The converse reaction, the conversion of energy to matter, has been observed frequently in the creation of many new elementary particles. The study of elementary particles has not solved the question of the nature of matter but only shifted it to a smaller scale.

Bibliography

See V. H. Booth, Elements of Physical Science: The Nature of Matter and Energy (1970); G. Amaldi, The Nature of Matter: Physical Theory from Thales to Fermi (1982).

In chemistry and physics, matter is commonly defined as the substance of which physical objects are composed, not counting the contribution of various energy or force-fields, which are not usually considered to be matter per se (though they may contribute to the mass of objects). Matter constitutes much of the observable universe, although again, light is not ordinarily considered matter. Unfortunately, for scientific purposes, "matter" is somewhat loosely defined.

Definition

Matter is the stuff which things are made of and consists of chemical substances. These are made of atoms, which are made of protons, neutrons and electrons. In this way, 'matter' is contrasted with 'energy'; inversely 'energy' is an expression of 'matter'. Everything in the world has matter.

In physics, there is no broad consensus as to an exact definition of "matter". Physicists generally do not use the word when precision is needed, preferring instead to speak of the more clearly defined concepts of mass, energy and particles.

A possible definition of matter which at least some physicists use ^[1] is that it is everything that is constituted of elementary fermions. These are the leptons, including the electron, and the quarks, including the up and down quarks of which protons and neutrons are made. Since protons, neutrons and electrons combine to form atoms, atoms, molecules and the bulk substances which they make up are all matter. Matter also includes the various baryons and mesons. Things which are not matter include light (photons) and the other gauge bosons.

However, this definition is not always satisfying when examined closely. In particular, under this definition things may have mass without being matter:

• W and Z bosons have mass, but are not elementary fermions.
• Any two photons which are not moving parallel to each other, taken as a system, have an invariant mass.
• Glueballs have mass due to their binding energy, but contain no particle with mass, nor any elementary fermions.

And they may be matter without having mass:

• Most of the mass of protons and neutrons comes from the binding energy between the quarks, not the masses of the quarks themselves.
• One of the three types of neutrinos may be massless.

Usage note regarding matter and anti-matter

There is a semantic difficulty with the word "matter", since it has two meanings, one of which includes the other. "Matter" may mean either:

1. The opposite of anti-matter (e.g. electrons, but not positrons)
2. Both matter as defined in the previous line and anti-matter (e.g. both electrons and positrons)

The same difficulty occurs with the word particle.

Properties of matter

As individual particles

Quarks combine to form hadrons. Because of the principle of color confinement which occurs in the strong interaction, quarks never exist unbound from other quarks. Among the hadrons are the proton and the neutron. Usually these nuclei are surrounded by a cloud of electrons. A nucleus with as many electrons as protons is thus electrically neutral and is called an atom, otherwise it is an ion.

Leptons do not feel the strong force and so can exist unbound from other particles. On Earth, electrons are generally bound in atoms, but it is easy to free them, a fact which is exploited in the cathode ray tube. Muons may briefly form bound states known as muonic atoms. Neutrinos feel neither the strong nor the electromagnetic interactions. They are never bound to other particles.^[1]

As bulk matter

Homogeneous matter has a definite composition and properties and any amount of it has the same composition and properties. It may be a mixture, such as brass, or elemental, like pure iron. Heterogeneous matter, such as granite, does not have a definite composition.

Phases

In bulk, matter can exist in several different phases, according to pressure and temperature. A phase is a state of a macroscopic physical system that has relatively uniform chemical composition and physical properties (i.e. density, crystal structure, index of refraction, and so forth). These phases include the three familiar ones — solids, liquids, and gases — as well as plasmas, superfluids, supersolids, Bose-Einstein condensates, fermionic condensates, liquid crystals, strange matter and quark-gluon plasmas. There are also the paramagnetic and ferromagnetic phases of magnetic materials. As conditions change, matter may change from one phase into another. These phenomena are called phase transitions, and their energetics are studied in the field of thermodynamics.

In small quantities, matter can exhibit properties that are entirely different from those of bulk material and may not be well described by any phase.

Phases are sometimes called states of matter, but this term can lead to confusion with thermodynamic states. For example, two gases maintained at different pressures are in different thermodynamic states, but the same "state of matter".

Antimatter

Main article: Antimatter

In particle physics and quantum chemistry, antimatter is matter that is composed of the antiparticles of those that constitute normal matter. If a particle and its antiparticle come into contact with each other, the two annihilate; that is, they may both be converted into other particles with equal energy in accordance with Einstein's equation E = mc². These new particles may be high-energy photons (gamma rays) or other particle–antiparticle pairs. The resulting particles are endowed with an amount of kinetic energy equal to the difference between the rest mass of the products of the annihilation and the rest mass of the original particle-antiparticle pair, which is often quite large.

Antimatter is not found naturally on Earth, except very briefly and in vanishingly small quantities (as the result of radioactive decay or cosmic rays). This is because antimatter which came to exist on Earth outside the confines of a suitable physics laboratory would almost instantly meet the ordinary matter that Earth is made of, and be annihilated. Antiparticles and some stable antimatter (such as antihydrogen) can be made in tiny amounts, but not in enough quantity to do more than test a few of its theoretical properties.

There is considerable speculation both in science and science fiction as to why the observable universe is apparently almost entirely matter, whether other places are almost entirely antimatter instead, and what might be possible if antimatter could be harnessed, but at this time the apparent asymmetry of matter and antimatter in the visible universe is one of the great unsolved problems in physics. Possible processes by which it came about are explored in more detail under baryogenesis.

Dark matter

Main article: Dark matter

In cosmology, most models of the early universe and big bang require the existence of so called dark matter. This matter would have energy and mass, but would NOT be composed of either elementary fermions (as above) OR gauge bosons. As such, it would be composed of particles unknown to present science. Its existence is inferential at this point.

References

1. ^ ^{a b} Povh, Rith, Scholz, Zetche, Particles and Nuclei, 1999, ISBN 3540438238

See also

• Particle physics

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