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An acyliminium is an acyl iminium ion - an ion of iminium, a form of quaternary ammonium formed by an imine.
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R2C=(NR2)+ Note: Nitrogen has a positive charge. It can be generated by treating an aldehyde or ketone with a primary or secondary amine.
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The Dakin oxidation is an organic redox reaction in which an ortho- or para-hydroxylated phenyl aldehyde (2-hydroxybenzaldehyde or 4-hydroxybenzaldehyde) or ketone reacts with hydrogen peroxide in base to form a benzenediol and a carboxylate. Overall, the carbonyl group is oxidized, and the hydrogen peroxide is reduced.
The Dakin oxidation, which is closely related to the Baeyer-Villiger oxidation, is not to be confused with the Dakin-West reaction, though both are named after Henry Drysdale Dakin
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