Greek fire
n.
An incendiary preparation first used by the Byzantine Greeks to set fire to enemy ships.
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An incendiary preparation first used by the Byzantine Greeks to set fire to enemy ships.
A combustible compound emitted by a flame-throwing weapon and used in ancient times to set light to enemy ships. It was first used by the Greeks besieged in Constantinople (673-78). It ignited on contact with water, and was probably based on naphtha and quicklime.
See the Introduction, Abbreviations and Pronunciation for further details.
For more information on Greek fire, visit Britannica.com.
For the 2007 series of fires, see 2007 Greek forest fires.
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| Greek Fire | |
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| Also called: | Byzantine fire wildfire sea fire liquid fire |
| Byzantine Greek: | υγρόν πυρ (ygròn pyr): "liquid fire" |
Greek fire was a burning-liquid weapon used by the Byzantine Greeks, Arabs, Chinese, and Mongols. The Byzantines typically used it in naval battles to great effect as it could continue burning even on water. It was largely responsible for many Byzantine military victories, and partly the reason for the Byzantine Empire surviving as long as it did. The formula was a secret and remains a mystery to this day. As one contemporary victim of Greek fire advised his comrades, "Every time they hurl the fire at us, we go down on our elbows and knees, and beseech Our Lord to save us from this danger."[1]
Theophanes records that Greek fire was invented c. 670 in Constantinople by Kallinikos (Callinicus), an architect from Heliopolis in the Byzantine Iudaea Province.[2] Historian James Partington thinks it likely that "Greek fire was really invented by the chemists in Constantinople who had inherited the discoveries of the Alexandrian chemical school".[3] Many accounts note that the fires it caused could not be put out by pouring water on the flames—on the contrary, the water served to intensify or spread them, suggesting that 'Greek fire' may have been a 'thermite-like' reaction, possibly involving a quicklime or similar compound. Others have posited a flammable liquid that floated on water, possibly a form of naphtha or another low-density liquid hydrocarbon, as petroleum was known to Eastern chemists long before its use became widespread in the 1800s.
In its earliest uses it was applied onto enemy forces by firing a burning cloth-wrapped ball, perhaps containing a flask, using a form of light catapult, most probably a sea-borne variant of the Roman light catapult or onager. These were capable of hurling light loads (c. six to nine kilograms—up to twenty pounds) 350-450 meters (approx. four to five hundred yards). Later technological improvements in machining technology enabled the devising of a pump mechanism discharging a stream of burning fluid (flame thrower) at close ranges, devastating wooden ships in naval warfare and also very effective on land as a counter-force suppression weapon used on besieging forces. There are many accounts of the Byzantine Empire driving off attacks on the walls using this devastatingly frightful secret formula.
The earliest reference to Greek fire in China was made in AD 917, written by the author Wu Ren-chen in his Shi Guo Chun Qiu.[4] The Chinese Emperor of Wu (with his capital at Hangzhou at the time) had presented the Khitan monarch Apaoki with a gift of 'fire oil', yet the Khitan Queen Shu Li advised against its use, saying it was better to attack enemies with cavalry than it was to attack with seemingly useless oil.[5] In AD 919, the siphon projector-pump was used to spread the "fierce fire oil" that could not be doused with water, as recorded by Lin Yu in his Wu Yue Bei Shi, hence the first credible Chinese reference to the flamethrower employing the chemical solution of Greek fire (see also Pen Huo Qi).[6] Lin Yu mentioned also that the 'fierce fire oil' derived ultimately from one of China's maritime contacts in the 'southern seas', Arabia (Dashiguo).[7] In a battle of AD 932, at the Battle of Langshan Jiang (Wolf Mountain River), the naval fleet of the Wen-Mu King was defeated by Qian Yuanguan because he had used 'fire oil' ('huo you') to burn his fleet, signifying the first Chinese use of gunpowder in a battle (see also blackpowder).[7] The Chinese applied the use of double-piston bellows (this double-set used since the Han Dynasty for smelting cast iron) to pump petrol out of a single cylinder (with an upstroke and downstroke). This fluid was lit at the end by a slow-burning gunpowder match to fire a continuous stream of flame, as referred to and illustrated in the Wujing Zongyao manuscript of AD 1044.[7] In the suppression of the Southern Tang state by AD 976, early Song Dynasty naval forces confronted them on the Yangtze River in AD 975. Southern Tang forces attempted to use flamethrowers against the Song navy, but were accidentally consumed by their own fire when violent winds swept in their direction.[8] The Song Dynasty continued use of the flamethrower, while the Chinese of this era also innovated the early grenade, firearm, land mine, and cannon.
Greek fire was largely responsible for many Byzantine military victories, and partly the reason the Eastern Roman Empire
survived as long as it did. It was particularly helpful near the end of the empire's life when there were not enough inhabitants
to effectively defend its territories. It was first used to repel the Muslim Arabs at the first Siege of Constantinople (674), the
Although similar substances have been invented in the modern age, the exact composition of the original Greek fire is unknown.
The effectiveness of Greek fire was indisputable; however, it was mainly effective under certain circumstances. For instance, it was less effective in the open sea than in narrow sea passages. Greek fire should not be considered an invention that solved all the maritime problems of the Byzantine Empire. Naval war continued to be based on the traditional art of maritime strategy, to which Greek fire added an effective weapon for the Byzantines.
The ingredients, process of manufacture, and usage were a very carefully guarded military secret—so secretive that it remains a source of speculation to this day. Speculations include
It is not clear if the operator ignited the mixture with a flame as it emerged from the syringe, or if it ignited spontaneously on contact with water or air. If the latter is the case, it is possible that the active ingredient was calcium phosphide, made by heating lime, bones, and charcoal. On contact with water, calcium phosphide releases phosphine, which ignites spontaneously. The reaction of quicklime with water also creates enough heat to ignite hydrocarbons, especially if an oxidizer such as saltpeter is present. However, Greek fire was also used on land.
These ingredients were apparently heated in a cauldron, and then pumped out through a siphon or large syringe (known as a siphònariòs) mounted on the bow of the ship. Such a ship was herself called a siphònòphòròs or dromon. It could also be used in hand grenades, made of earthenware vessels. If a pyrophoric reaction was involved, perhaps these grenades contained chambers for the fluids, which mixed and ignited when the vessel broke on impact with the target.
The Memoirs of Jean de Joinville, a thirteenth century French nobleman, include these observations of Greek fire during the Seventh Crusade:[1]
The Dream Pool Essays observes that "There are Buddhist books which speak of 'dragon fire' which burns more fiercely when it meets with water instead of being extinguished by water like 'human' fire. Most people can only judge of things by the experiences of ordinary life, but phenomena outside the scope of this are really quite numerous. How insecure it is to investigate natural principles using only the light of common knowledge, and subjective ideas."[12]
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