fire extinguisher
n.
A portable apparatus containing chemicals that can be discharged in a rapid stream to extinguish a small fire.
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A portable apparatus containing chemicals that can be discharged in a rapid stream to extinguish a small fire.
Background
The hand-held fire extinguisher is simply a pressure vessel from which is expelled a material (or agent) to put out a fire. The agent acts upon the chemistry of the fire by removing one or more of the three elements necessary to maintain fire—commonly referred to as the fire triangle. The three sides of the fire triangle are fuel, heat, and oxygen. The agent acts to remove the heat by cooling the fuel or to produce a barrier between the fuel and the oxygen supply in the surrounding air. Once the fire triangle is broken, the fire goes out. Most agents have a lasting effect upon the fuel to reduce the possibility of rekindling. Generally, the agents applied are water, chemical foam, dry powder, halon, or carbon dioxide (CO2). Unfortunately, no one agent is effective in fighting all types (classes) of fires. The type and environment of the combustible material determines the type of extinguisher to be kept nearby.
History
Fire extinguishers, in one form or another, have probably postdated fire by only a short time. The more practical and unitized extinguisher now commonplace began as a pressurized vessel that spewed forth water, and later, a combination of liquid elements. The older extinguishers comprised cylinders containing a solution of baking soda (sodium bicarbonate) and water. Inside, a vessel of sulfuric acid was positioned at the top of the body. This design had to be turned upside down to be activated, so that the acid spilled into the sodium bicarbonate solution and reacted chemically to form enough carbon dioxide to pressurize the body cylinder and drive out the water through a delivery pipe. This volatile device was improved by placing the acid in a glass bottle, designed to be broken by a plunger set on the top of the cylinder body or by a hammer striking a ring contraption on the side to release the acid. Cumbersome and sometimes ineffective, this design also required improvement.
Design
Aside from using different agents, manufacturers of extinguishers generally use some type of pressurized vessel to store and discharge the extinguishing agent. The means by which each agent is discharged varies. Water fire extinguishers are pressurized with air to approximately 150 pounds per square inch (psi)—five times a car tire pressure—from a compressor. A squeeze-grip handle operates a spring-loaded valve threaded into the pressure cylinder. Inside, a pipe or "dip tube" extends to the bottom of the tank so that in the upright position, the opening of the tube is submerged. The water is released as a steady stream through a hose or nozzle, pushed out by the stored pressure above it.
Water extinguishers of the "gas cartridge" type operate in much the same manner, but the pressure source is a small cartridge of carbon dioxide gas (CO2) at 2,000 psi, rather than air. To operate a gas cartridge unit, the end of the extinguisher is struck against the floor, causing a pointed spike to pierce the cartridge, releasing the gas into the pressure vessel. The released CO2 expands several hundred times its original volume, filling the gas space above the water. This pressurizes the cylinder and forces the water up through a dip-pipe and out through a hose or nozzle to be directed upon the fire. This design proved to be less prone to leakdown (loss of pressure over time) than simply pressurizing the entire cylinder.
In foam extinguishers, the chemical agent is generally held under stored pressure. In dry powder extinguishers, the chemicals can either be put under stored pressure, or a gas cartridge expeller can be used; the stored-pressure type is more widely used. In carbon dioxide extinguishers, the CO2 is retained in liquid form under 800 to 900 psi and is "self-expelling," meaning that no other element is needed to force the CO2 out of the extinguisher. In halon units, the chemical is also retained in liquid form under pressure, but a gas booster (usually nitrogen) is generally added to the vessel.
Raw Materials
Fire extinguishers can be divided into four classifications: Class A, Class B, Class C, and Class D. Each class corresponds to the type of fire the extinguisher is designed for, and, thus, the type of extinguishing agents used. Class A extinguishers are designed to fight wood and paper fires; Class B units fight contained flammable liquid fires; Class C extinguishers are designed to fight live electrical fires; and Class D units fight burning metal fires.
Water has proven effective in extinguishers used against wood or paper fires (Class A). Water, however, is an electrical conductor. Naturally, for this reason, it is not safe as an agent to fight electrical fires where live circuits are present (Class C). In addition, Class A extinguishers should not to be used in the event of flammable liquid fires (Class B), especially in tanks or vessels. Water can cause an explosion due to flammable liquids floating on the water and continuing to burn. Also, the forceful water stream can further splatter the burning liquid to other combustibles. One disadvantage of water extinguishers is that the water often freezes inside the extinguisher at lower temperatures. For these reasons, foam, dry chemical, CO2, and halon types were developed.
Foam, although water based, is effective against fires involving contained flammable liquids (Class B). A two-gallon (7.5 liters) extinguisher will produce about 16 gallons (60 liters) of thick, clinging foam that cools and smothers the fire. The agent itself is a proprietary compound developed by the various manufacturers and contains a small amount of propylene glycol to prevent freezing. It is contained as a mixture in a pressurized cylinder similar to the water type. Most aircraft carry this type of extinguisher. Foam can also be used on Class A fires.
The dry powder agent was developed to reduce the electrical hazard of water, and thus is effective against Class C fires. (It can also be used against Class B fires.) The powder is finely divided sodium bicarbonate that is extremely free-flowing. This extinguisher, also equipped with a dip-tube and containing a pressurizing gas, can be either cartridge-operated or of the stored pressure type as discussed above. Many specialized dry chemical extinguishers are also suitable for burning metal fires, or Class D.
Carbon dioxide (CO2) extinguishers, effective against many flammable liquid and electrical fires (Class B and C), use CO2 as both the agent and the pressurizing gas. The liquified carbon dioxide, at a pressure that may exceed 800 psi depending on size and use, is expelled through a flared horn. Activating the squeeze-grip handle releases the CO2 into the air, where it immediately forms a white, fluffy "snow." The snow, along with the gas, substantially reduces the amount of oxygen in a small area around the fire. This suffocates the fire, while the snow clings to the fuel, cooling it below the combustion point. The greatest advantage to the CO2 extinguisher is the lack of permanent residue. The electrical apparatus that was on fire is then more likely to be able to be repaired. Unlike CO2 "snow," water, foam, and dry chemicals can ruin otherwise undamaged components.
As extinguishing agents, halons are up to ten times more effective in putting out fires than other chemicals. Most halons are non-toxic and extremely fast and effective. Chemically inert, they are harmless to delicate equipment, including computer circuits, and leave no residue. The advantage of the halon over the CO2 extinguisher is that it is generally smaller and lighter. Halon is a liquid when under pressure, so it uses a dip-tube along with nitrogen as the pressurizing gas.
Halon, at least in fire extinguishers, may soon become a footnote to history. In 1992, 87 nations around the world agreed to halt the manufacture of halon fire extinguishers by January 1, 1994. This will eliminate a potential threat to the earth's protective ozone layer, which halon molecules—highly resistant to decomposition—interact with and destroy.
Most of the other elements of a fire extinguisher are made of metal. The pressure vessel is generally made of an aluminum alloy, while the valve can either be steel or plastic. Other components, such as the actuating handle, safety pins, and mounting bracket, are typically made of steel.
The Manufacturing
Process
Manufacture of the tank-type or cylinder fire extinguisher requires several manufacturing operations to form the pressure vessel, load the chemical agent, machine the valve, and add the hardware, hose, or nozzle.
Creating the pressure vessel
Necking and spinning
Adding the extinguishing agent
Final assembly
Quality Control
All fire extinguishers in the United States fall under the jurisdiction of the National Fire Protection Association (NFPA), Under-writer's Laboratories, The Coast Guard, and other organizations such as the New York Fire Department. Manufacturers must register their design and submit samples for evaluation before marketing an approved fire extinguisher.
One of the most crucial checkpoints during the manufacturing process occurs after the extinguishing agent is added and the vessel sealed. It is extremely important that the cylinder not leak down the pressurizing gas, because that would render the extinguisher useless. To check for leaks, a boot is placed over the cylinder to serve as an accumulator. A trace gas is released inside, and within two minutes any unacceptable rate of leakage can be recorded by sophisticated pressure and gas-detecting equipment. All extinguishers are leak tested.
The Future
With the gradual elimination of halon, a new, non-damaging agent will most likely replace the hazardous chemical within the next few years. In addition, new applications of the old designs are being seen; most prevalent are automatic heat and fire sensors that discharge the extinguisher without the need for an operator.
Where To Learn More
Books
Fire Prevention Handbook. Butterworths, London, 1986.
Mahoney, Gene. Introduction to Fire Apparatus & Equipment. 2nd ed., Fire Engineering Books & Videos, 1986.
Pamphlets
Portable Fire Extinguishing Equipment in Family Dwellings & Living Units. National Fire Protection Association, 1992.
[Article by: Douglas E. Betts and; Peter Toeg]
Fire may be extinguished by the following methods: (1) cooling the burning materials; (2) blanketing the fire with inert gas that chokes it for lack of oxygen; (3) introducing materials that inhibit combustion; and (4) covering the burning matter with a blanket or a layer of solid particles that prevent access of air. Fire extinguishers operate on one or a combination of these principles.
Water is the most effective cooling agent used in fire extinguishing. The generation of steam also drives away the air and forms a blanket, but being less dense than air, it is rapidly displaced. Wetting agents and foaming agents increase the effectiveness of water. In the small, first-aid, water fire extinguishers, a propellant must be provided. Usually this is carbon dioxide, which is either generated when needed or stored in a cartridge. Water should not be used on oil fires or on electrical fires.
Automatic water sprinkler systems are a common form of fire protection in industrial plants and large buildings. The installation of these systems is the greatest single factor to be credited for the sharply reduced incidence of disastrous fires in recent years. See also Automatic sprinkler system.
Carbon dioxide is a safe and effective extinguisher for all confined fires. It acts as an inert blanket, and because it is heavier than air, it will exclude oxygen very efficiently from a fire on the floor of a building or in a vat or similar vessel. It is not effective in an elevated location or outdoors where the wind can blow the gas away.
A dry powder, consisting principally of sodium bicarbonate, may also be used as a fire extinguisher. The powder must have the correct particle size and contain materials that prevent it from caking. The action of the powder is threefold: to generate carbon dioxide; to cool the burning material; and to provide a shielding to prevent access of air. Dry chemical is useful for small fires, and especially electrical fires.
Carbon tetrachloride, CCl4, has had a long history as a fire-extinguishing agent. As it is customarily used, in small quantities, the principal action is to supply a heavy blanket of vapor over the fire. In addition, carbon tetrachloride, in common with all the halogenated compounds, has a definite chemical inhibiting effect on combustion. Other halogenated hydrocarbons that have been used are chlorobromomethane, and several of the fluorinated hydrocarbons known as freons. The principal difficulty, however, with all the halogenated hydrocarbons, and with CCl4, in particular, is toxicity.
Other extinguishing methods should be mentioned that require no special equipment. For a household fire, especially involving clothing on a person, a blanket or a rug provides an effective means to smother the fire. Small fires around a kitchen stove may be snuffed out with salt or, better still, with bicarbonate of soda. A bucket of sand, strategically located, is also useful against domestic fire hazards.
Instrument that uses noncombustible substances such as carbon dioxide to deprive a fire of oxygen, thereby extinguishing it.
A portable device, for immediate and temporary use in putting out a fire: class A: used on fires involving ordinary combustible materials (such as wood, cloth, paper, rubber, and many plastics), which require the cooling effects of water or certain dry chemical coatings to retard combustion; class B: used on fires involving liquids, gases, greases, etc., extinguished most readily by excluding air or inhibiting the release of combustible vapors; class C: used on fires in “live” electrical equipment; class D: used on fires involving certain combustible metals, such as magnesium, sodium, etc., requiring a heat-absorbing extinguishing medium not reactive with the burning metals.
A fire extinguisher is an active fire protection device used to extinguish or control small fires, often in emergency situations. Typically, a fire extinguisher consists of a handheld cylindrical pressure vessel containing an agent which can be discharged to extinguish a fire.
The typical steps for operating a stored pressure fire extinguisher (described by the acronym "PASS") are the following:
There are various types of extinguishers, which are used for different types of fires; using the wrong type can worsen the fire hazard, but using the right one can better the situation.
The first automatic fire extinguisher of which there is any record was patented in England in 1723 by Ambrose Godfrey, a celebrated chemist. It consisted of a cask of fire-extinguishing liquid containing a pewter chamber of gunpowder. This was connected with a system of fuses which were ignited, exploding the gunpowder and scattering the solution. This device was probably used to a limited extent, as Bradley's Weekly Messenger for November 7, 1729, refers to its efficiency in stopping a fire in London.
The modern fire extinguisher was invented by British Captain George William Manby in 1818; it consisted of a copper vessel of 3 gallons (13.6 litres) of pearl ash (potassium carbonate) solution contained within compressed air.
The soda-acid extinguisher was invented in the 19th century, which contained a cylinder of 1 or 2 gallons of water with sodium bicarbonate mixed into it. A vial was suspended in the cylinder containing concentrated sulphuric acid. Depending on the type of extinguisher, the vial of acid could be broken in one of two ways. One used a plunger to break the acid vial, while the second released a lead bung that held the vial closed. Once the acid was mixed with the bicarbonate solution, carbon dioxide gas was expelled and thereby pressurize the water. The pressurized water was forced from the canister through a nozzle or short length of hose.
Around 1912 Pyrene invented the carbon tetrachloride or CTC extinguisher, which expelled the liquid from a brass or chrome container by a handpump; it was usually of 1 imperial quart (1.1 L) or 1 imperial pint (0.6 L) capacity but was also available in up to 2 imperial gallon (9 L) size. A further variety consisted of a glass bottle "bomb" filled with the liquid that was intended to be hurled at the base of a fire. The CTC vaporized and extinguished the flames by chemical reaction. The extinguisher was suitable for liquid and electrical fires, and was popular in motor vehicles for the next 60 years. The vapor and combustion by-products were highly toxic, and could cause death in confined spaces.
Internationally there are several accepted classification methods for hand-held fire extinguishers. Each classification is useful in fighting fires with a particular group of fuel.
| Type | Pre-1997 | Current | Class | ||||
|---|---|---|---|---|---|---|---|
| Water | Solid red | A | |||||
| Foam | Solid blue | Red with a blue band | A | B | |||
| Powder | Red with a white band | A | B | C | E | ||
| Carbon dioxide | Red with a black band | A (limited) | B | C | E | F | |
| Vapourising liquid (not halon) | Red with a yellow band | A | B | C | E | ||
| Halon | Solid yellow | — | A | B | E | ||
| Wet chemical | Solid oatmeal | Red with an oatmeal band | A | F | |||
In Australia, yellow (Halon) fire extinguishers are illegal to own or use on a fire, unless an essential use exemption has been granted.[1]
According to the standard BS EN 3, fire extinguishers in the United Kingdom as all throughout Europe are red RAL 3000, and a band or circle of a second color covering at least 5% of the surface area of the extinguisher indicates the contents. Before 1997, the entire body of the fire extinguisher was color coded according to the type of extinguishing agent.
| Type | Old Code | BS EN 3 Colour Code | Fire Class | |||||
|---|---|---|---|---|---|---|---|---|
| Water | Signal Red | Signal Red | A | |||||
| Foam | Cream | Red with a Cream panel above the operating instructions | A | B | sometimes E | |||
| Dry Powder | French Blue | Red with a Blue panel above the operating instructions | A | B | C | E | ||
| Carbon Dioxide CO2 | Black | Red with a Black panel above the operating instructions | A (Limited) | B | E | |||
| Halon | Emerald Green | Pre-03- Signal red with a green panel | A | B | E | |||
| Wet Chemical | No F Class | Red with a Canary Yellow panel above the operating instructions | A | F | ||||
| Class D Powder | French Blue | Red with a Blue panel above the operating instructions | D | |||||
The UK recognizes six fire classes. Class A fires involve organic solids such as paper and wood. Class B fires involve flammable liquids. Class C fires involve flammable gases. Class D fires involve metals, Class E fires involve live electrical items and Class F fires involve cooking fat and oil. Fire extinguishing capacity is rated by fire class using numbers and letters such as 13A, 55B. EN 3 does not recognize a separate E class - this is an additional feature requiring special testing (dielectric test per EN 3-7:2004) and NOT passing this test makes it compulsory to add a special label (pictogram) indicating the inability to isolate the user from a live electric source.
In the UK the use of Halon gas is now illegal except under certain situations. [2]
There is no official standard in the United States for the color of fire extinguishers, though they are typically red, except for Class D extinguishers, which are usually yellow. Extinguishers are marked with pictograms depicting the types of fires that the extinguisher is approved to fight. In the past, extinguishers were marked with colored geometric symbols, and some extinguishers still use both symbols. No official pictogram exists for Class D extinguishers, though training manuals sometimes show a drill press with shavings burning underneath. The types of fires and additional standards are described in NFPA 10: Standard for Portable Fire Extinguishers.
| Fire Class | Geometric Symbol | Pictogram | Intended Use |
|---|---|---|---|
| A | Green Triangle | Garbage can and wood pile burning | Ordinary combustibles |
| B | Red Square | Gasoline can with a burning puddle | Flammable liquids and gases |
| C | Blue Circle | Electric plug with a burning outlet | Energized electrical equipment |
| D | Yellow Star | Drill press with burning shavings (not official) | Combustible metals |
| K | Black Hexagon | Pan burning | Cooking oils |
The Underwriters Laboratories rate fire extinguishing capacity in accordance with UL/ANSI 711: Rating and Fire Testing of Fire Extinguishers. The ratings are described using numbers preceding the class letter, such as 1-A:10-B:C. The number preceding the A multiplied by 1.25 gives the equivalent extinguishing capability in gallons of water. The number preceding the B indicates the size of fire in square feet that an ordinary user should be able to extinguish. There is no additional rating for class C, as it only indicates that the extinguishing agent will not conduct electricity, and an extinguisher will never have a rating of just C.
Fire extinguishers are typically fitted in buildings at an easily-accessible location, such as against a wall in a high-traffic area. They are also often fitted to motor vehicles, watercraft, and aircraft - this is required by law in many juristictions, for identified classes of vehicles. Under NFPA 10 all commercial vehicles must carry at least one fire extinguisher (size/UL rating depending on type of vechical and cargo (ie. fuel tankers typically must have a 20lb. when most others can carry a 5lb.) The revised NFPA 10 created criteria on the placement of "Fast Flow Extinguishers" in locations such as those storing and transporting pressurized flammable liquids and pressurized flammable gas or areas with possiblity of three dimensional class B hazards are required to have "fast flow" extinguishers as required by NFPA 5.5.1.1.
Varying classes of competition vehicles require fire extinguishing systems, the simplest requirements being a 1A10BC handheld portable extinguisher mounted to the interior of the vehicle.
Powder based agent that extinguishes by inhibiting the free radicals produced by combustion. It has no cooling or smothering effect and a partially extinguished fire will flash back.
Mixed with water and applied to fuel fires as either an aspirated (mixed & expanded with air in a branch pipe) or non aspirated form to form a frothy blanket or seal over the fuel, preventing oxygen reaching it. Unlike powder, foam can be used to progressively extinguish fires without flashback
Cools burning material
Agent does not extinguish by smothering, but displaces oxygen, or inhibits chemical chain reaction. They are labeled clean agents because they do not leave any residue after discharge which is ideal for sensitive electronics and documents.
Most countries in the world require regular fire extinguisher maintenance by a competent person to operate safely and effectively, as part of fire safety legislation. Lack of maintenance can lead to an extinguisher not discharging when required, or rupturing when pressurized. Deaths have occurred, even in recent times, from corroded extinguishers exploding.
There is no all-encompassing fire code in the United States. Generally, most municipalities (by adoption of the International Fire Code) require inspections every 30 days to ensure the unit is pressurized and unobstructed (done by an employee of the facility) and an annual inspection by a qualified technician. Hydrostatic pressure testing for all types of extinguishers is also required, generally every five years for water and CO2 models up to every 12 years for dry chemical models.
Recently the National Fire Protection Association and ICC voted to allow for the elimination of the 30 day inspection requirement so long as the fire extinguisher is monitored electronically. According to NFPA, the system must provide record keeping in the form of an electronic event log at the control panel. The system must also constantly monitor an extinguisher’s physical presence, internal pressure and whether an obstruction exists that could prevent ready access. In the event that any of the above conditions are found, the system must send an alert to officials so they can immediately rectify the situation. Electronic monitoring can be wired or wireless.
In the UK, three types of maintenance are required:
Automatic Sprinkler Protection - Goram Dana, S.B.
| Fire protection | |
|---|---|
| General: Active fire protection — Fire alarm system Fire suppression: Fire extinguisher — Fire sand
bucket — Fire sprinkler — Gaseous fire
suppression |
|
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