Yes, physical adsorption typically has a low adsorption enthalpy due to weak van der Waals forces between the adsorbate and adsorbent. These interactions are reversible and non-specific, leading to lower enthalpies compared to chemical adsorption.
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Yes, the adsorption capacity of an adsorbent is influenced by its porosity. A higher porosity provides more surface area for adsorption to occur, resulting in a greater adsorption capacity. Therefore, materials with higher porosity generally exhibit higher adsorption capabilities.
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Physical adsorption is reversible because the forces involved are weak van der Waals forces, such as London dispersion forces or dipole-dipole interactions. These forces can be easily disrupted by changes in temperature or pressure, allowing the adsorbate to be released from the adsorbent surface. This reversibility distinguishes physical adsorption from chemical adsorption, which involves stronger, more covalent bonds.
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Lawrence T. Drzal has written:
'Adsorbate-adsorbent interactions by gas adsorption' -- subject(s): Absortion and adsorption, Gases, Adsorption
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An adsorption site is a location on a surface where molecules or particles can adhere or bind due to attractive forces. It is where adsorption occurs, where a substance accumulates on the surface of another material. Adsorption sites are important in processes like catalysis, gas separation, and water treatment.
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In reality, adsorption is a process where molecules in a gas or liquid adhere to the surface of a solid. This occurs due to the attractive forces between the molecules and the solid surface. Adsorption is used in various applications such as purifying gases, wastewater treatment, and catalysts.
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Douglas M. Ruthven has written:
'Pressure swing adsorption' -- subject(s): Adsorption
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Roberto Triolo has written:
'Adsorption on mixtures of ion exchanges' -- subject(s): Ion exchange, Adsorption
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Matthew H Lang has written:
'Polyelectrolyte adsorption kinetics' -- subject(s): Polyelectrolytes, Adsorption
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Yes, adsorption is a process in which one substance (the adsorbate) is attracted and binds to the surface of another material (the adsorbent) through physical or chemical interactions. This results in a concentration of the adsorbate at the surface of the adsorbent.
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Gregory R. Bean has written:
'Adsorption of hexavalent and trivalent chromium to a clayey silt soil' -- subject(s): Absorption and adsorption, Chromium, Environmental aspects, Environmental aspects of Chromium, Soil absorption and adsorption
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put the beads in bacterial liquid culture for some day for adsorption. check the coating by
conducting SEM surface topology.
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Patricia Ann Shields has written:
'Factors influencing virus adsorption to solids' -- subject(s): Viruses, Adsorption (Biology)
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Darrell Vance Sickman has written:
'Adsorption and reactions at surfaces of zinc oxide ..' -- subject(s): Adsorption, Zinc oxide
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Adsorption occurs due to the attractive forces between molecules of a solid surface and molecules or ions in a fluid or gas. These attractive forces lead to the accumulation of the molecules or ions on the surface of the solid, creating a thin layer. Adsorption can be influenced by factors such as the surface area and nature of the adsorbent and the concentration and properties of the adsorbate.
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Frenlich adsorption isotherm has no theoretical basis. There are high chances of it failing when the concentration of the adsorbate is high. The equation is, usually, invalid at high pressure.
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the adsorption capacity of calcium is 0.78 kg/ kg of calcium chloride from one article on adsorption cycle
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Mohd H. Hassan has written:
'Electrostatic effects on surfactant adsorption' -- subject(s): Electrostatics, Surface active agents, Adsorption
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The Freundlich isotherm describes multilayer adsorption onto a heterogeneous surface with non-specific interactions, while the Langmuir isotherm describes monolayer adsorption onto a homogeneous surface with specific interactions. Freundlich assumes a continuous distribution of energies for adsorption, whereas Langmuir assumes a finite number of identical sites for adsorption.
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Freundlich adsorption isotherm assumes a homogeneous surface with a finite number of adsorption sites, making it unsuitable for high pressures where interactions between adsorbate molecules become significant. At high pressures, multilayer adsorption occurs, violating the assumptions of the Freundlich isotherm which fails to account for these complex interactions. As a result, Freundlich isotherm is not applicable in conditions where multilayer adsorption dominates.
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Adsorption is the process by which molecules of a substance adhere to the surface of another substance, while condensation is the phase transition from gas to liquid when molecules lose energy and come together to form a liquid. Adsorption involves surface attraction, whereas condensation involves a change in physical state.
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Adsorption is exothermic because when molecules of an adsorbate adhere to a surface, they release energy in the form of heat due to increased interactions between the adsorbate and the surface. This results in a decrease in the overall energy of the system, making the process exothermic.
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desorption-changing from an adsorbed state on a surface to a gaseous or liquid state and adsorption-the accumulation of molecules of a gas to form a thin film on the surface of a solid
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Akio Ogata has written:
'Mathematics of dispersion with linear adsorption isotherm' -- subject(s): Mathematical models, Dispersion, Porosity, Fluid dynamics, Adsorption
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Adsorption is the process by which a substance is attached to the surface of a solid material. Biosorption, on the other hand, involves the use of living or dead biomass to remove pollutants from a solution. Biosorption is a specific type of adsorption that relies on biological processes to remove contaminants.
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Wassana Yantasee has written:
'Adsorption of calcium and nickel ions on wood pulp' -- subject(s): Wood-pulp, Metal ions, Washing, Absorption and adsorption
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Md. Akram Hossain has written:
'Modeling of activated carbon adsorption in a fixed bed' -- subject(s): Activated Carbon, Adsorption, Carbon, Activated
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James Procter Murray has written:
'Physical chemistry of virus adsorption and degradation on inorganic surfaces' -- subject(s): Purification, Sewage, Poliovirus, Adsorption
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Carol A. Lake has written:
'Phosphate and tripolyphosphate adsorption by clay minerals and estuarine sediments' -- subject(s): Adsorption, Clay minerals, Estuaries, Estuarine sediments, Phosphates
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V. F. Kiselev has written:
'Adsorption and catalysis on transition metals and their oxides' -- subject(s): Adsorption, Catalysis, Metallic oxides, Transition metal catalysis
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In adsorption, Gibbs free energy decreases because the adsorbate molecules are attracted to the surface of the adsorbent, reducing the overall energy of the system. This leads to a more stable configuration with a lower free energy. The decrease in Gibbs free energy indicates that the adsorption process is spontaneous at a given temperature and pressure.
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Yes, the phenomenon of adsorption is relevant in commercial valves, especially in industries where contamination or deposition of materials can affect valve performance. Adsorption can lead to material build-up on valve surfaces, affecting sealing, flow control, and overall efficiency. Proper material selection and maintenance practices can help mitigate adsorption effects in commercial valves.
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The acetic acid molecules will be attracted to the surface of the charcoal due to adsorption, leading to their accumulation on the charcoal's surface. This process can be used to remove acetic acid from a solution through physical adsorption without undergoing a chemical reaction.
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The lambda max for Congo red dye adsorption typically lies around 497-498 nm, which represents the wavelength at which the dye molecule absorbs light most strongly. This specific wavelength can be used to monitor the adsorption process of Congo red dye onto different surfaces or materials.
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An adsorbent is the solid or liquid in the process of adsorption on which the adsorbate accumulates.
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Stephen Brunauer has written:
'Adsorption of gases'
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At a given temperature, the extent of adsorption will increase with the increase of pressure of the gas. The extent of adsorption is measured as x/m, where mi= is the mass of adsorbent and x that of adsorbate. At low pressure, x/m varies linearly with p.
As per Freundlich adsorption equation Taking log both sides of the equation, we get, At low pressure, x/m=kP At high pressure, x/m=kPo This is called Freundlich adsorption isotherm at a constant temperature.
Freundlich isotherm fails at high pressure and is only for physical adsorption. Langmuir isotherm is represented as
x/m=ap/(1+bp) (a and b are constants)
At very high pressure,(bp>>1)
x/m=a/b
At very low pressure,(bp<<1)
x/m=ap
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Yes, adsorption is typically a spontaneous process because it involves the attraction of molecules to a surface due to the energetically favorable interactions between them. This can result in a decrease in free energy and an increase in the stability of the system.
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Structure can provide a larger surface area for adsorption to occur, allowing more molecules to come into contact with the adsorbent material. It can also create smaller pores or channels that can trap molecules more effectively. Additionally, a well-defined structure can provide more active sites for molecules to bind to, increasing the efficiency of the adsorption process.
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A carbosphere is a carbonaceous material with a porous structure that can be used for applications such as water purification, gas adsorption, and energy storage. It is a type of carbon material that can have high surface area and excellent adsorption properties due to its physical structure.
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Yes,both can performed in columns.
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The rate of adsorption is influenced by factors such as surface area of the adsorbent, concentration of the adsorbate in the solution, temperature, polarity of the adsorbate and adsorbent, and the presence of impurities or competing adsorbates. These factors affect the driving forces for adsorption and the interactions between the adsorbent and adsorbate molecules, ultimately impacting the rate at which adsorption occurs.
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The flasks are stoppered during the adsorption of acetic acid by charcoal to prevent the loss of acetic acid vapors into the atmosphere. This allows for better control of the experiment, ensuring that the adsorption process occurs within the enclosed flask and the concentration of acetic acid is maintained.
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